EVALUATION OF ENERGETIC HETEROGENEITY AND MICROPOROSITY OF ACTIVATED CARBON-FIBERS ON THE BASIS OF GAS-ADSORPTION ISOTHERMS

被引：48

作者：

JARONIEC, M

GILPIN, RK

KANEKO, K

CHOMA, J

机构：

[1] CHIBA UNIV,DEPT CHEM,CHIBA 260,JAPAN

[2] WARSAW ACAD POLYTECH INST,INST CHEM,PL-00908 WARSAW,POLAND

来源：

LANGMUIR | 1991年 / 7卷 / 11期

关键词：

D O I：

10.1021/la00059a052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Measurements of low-temperature nitrogen adsorption isotherms are used to study the energetic heterogeneity and microporosity of cellulose- and poly(acrylonitrile)-based activated carbon fibers. The energetic heterogeneities of these materials are characterized by adsorption potential distribution functions which are the composite of two overlapping peaks that arise from the adsorbents biporous microstructures. A two-term Dubinin-Radushkevich equation is used to model the micropore-filling mechanism in the materials.

引用

页码：2719 / 2722

页数：4

共 54 条

[51] THE DYNAMIC STRUCTURAL-CHANGE OF HIGH SURFACE-AREA MICROCRYSTALS OF GRAPHITE WITH N-2 ADSORPTION [J].