SILICON-CARBON UNSATURATED-COMPOUNDS .48. SYNTHESIS AND REACTIONS OF SILICON ANALOGS OF LITHIUM ENOLATES

被引：26

作者：

OHSHITA, J

MASAOKA, Y

MASAOKA, S

ISHIKAWA, M

TACHIBANA, A

YANO, T

YAMABE, T

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIGASHIHIROSHIMA 724,JAPAN

[2] KYOTO UNIV,FAC ENGN,DEPT HYDROCARBON CHEM,KYOTO 606,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 473卷 / 1-2期

关键词：

SILICON; LITHIUM; UNSATURATED COMPOUNDS; LITHIUM ENOLATES;

D O I：

10.1016/0022-328X(94)80100-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of mesitoyl- and (2-methylbenzoyl)tris(trimethylsilyl)silane with 1 equiv. of a silyllithium gave silicon analogs of lithium enolates. Hydrolysis of the lithium silenolates afforded hydrosilanes in high yields. The lithium silenolates can be readily transformed into silenes quantitatively, by treatment with a chlorosilane.

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页码：15 / 17

页数：3

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