A NOVEL ROUTE TO THE TRISILACYCLOBUTANE MOIETY - A POSSIBLE SILENE DISILENE REACTION

被引：32

作者：

BRAVOZHIVOTOVSKII, D

APELOIG, Y

OVCHINNIKOV, Y

IGONIN, V

STRUCHKOV, YT

机构：

[1] TECHNION ISRAEL INST TECHNOL,DEPT CHEM,IL-32000 HAIFA,ISRAEL

[2] INEOS,MOSCOW 1178133,RUSSIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 446卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80043-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (Me3Si)3SiC(=O)Ad with a two-fold excess of Et3GeLi in THF, gives a 1:2 mixture of: 1,1,2,2-tetra-(trimethylsilyl)-3-trimethylsilyl-3-triethylgermoxy, 4-(1-adamantyl)-trisilacyclobutane (4) and adamantoyladamantyl-carbinol (5). The crystal structure of 4 is described and discussed. It is suggested that the trisilacyclobutane skeleton is formed by a cycloaddition reaction between a silene and a disilene.

引用

页码：123 / 129

页数：7

共 28 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] CRYSTAL-STRUCTURES OF 4 STERICALLY CROWDED 1,3-DISILACYCLOBUTANES
BAINES, KM
BROOK, AG
LICKISS, PD
SAWYER, JF
[J]. ORGANOMETALLICS, 1989, 8 (03) : 709 - 716
[3] SYNTHESIS AND STRUCTURE OF LITHIUM TRIS(TRIMETHYLSILYL)SILANIDE.1,5 DME
BECKER, G
HARTMANN, HM
MUNCH, A
RIFFEL, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 530 (11): : 29 - 42
[4] SILA-ENOLATE AND GERMA-ENOLATE ANIONS - THE REACTION OF ACYLGERMANES WITH TRIETHYLGERMYLLITHIUM
BILTUEVA, IS
BRAVOZHIVOTOVSKII, DA
KALIKHMAN, ID
VITKOVSKII, VY
SHEVCHENKO, SG
VYAZANKIN, NS
VORONKOV, MG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (02) : 163 - 165
[5] BRAVOZHIVOTOVSK.D, IN PRESS ORGANOMETAL
[6] RELATIVELY STABLE SILAETHYLENES - PHOTOLYSIS OF ACYLPOLYSILANES
BROOK, AG
HARRIS, JW
LENNON, J
ELSHEIKH, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (01) : 83 - 95
[7] A SOLID SILAETHENE - ISOLATION AND CHARACTERIZATION
BROOK, AG
ABDESAKEN, F
GUTEKUNST, B
GUTEKUNST, G
KALLURY, RK
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (04) : 191 - 192
[8] STABLE SOLID SILAETHYLENES
BROOK, AG
NYBURG, SC
ABDESAKEN, F
GUTEKUNST, B
GUTEKUNST, G
KALLURY, RKMR
POON, YC
CHANG, YM
WONGNG, W
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) : 5667 - 5672
[9] REACTIONS OF STABLE SILENES WITH GRIGNARD-REAGENTS
BROOK, AG
CHIU, P
MCCLENAGHNAN, J
LOUGH, AJ
[J]. ORGANOMETALLICS, 1991, 10 (09) : 3292 - 3301
[10] OCTAKIS(TRIMETHYLSILYL)CYCLOTETRASILANE - A STABLE CYCLOTETRASILANE FROM A SILYLENE PRECURSOR
CHEN, YS
GASPAR, PP
[J]. ORGANOMETALLICS, 1982, 1 (10) : 1410 - 1412

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