A NOVEL ROUTE TO THE TRISILACYCLOBUTANE MOIETY - A POSSIBLE SILENE DISILENE REACTION

被引：32

作者：

BRAVOZHIVOTOVSKII, D

APELOIG, Y

OVCHINNIKOV, Y

IGONIN, V

STRUCHKOV, YT

机构：

[1] TECHNION ISRAEL INST TECHNOL,DEPT CHEM,IL-32000 HAIFA,ISRAEL

[2] INEOS,MOSCOW 1178133,RUSSIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 446卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80043-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of (Me3Si)3SiC(=O)Ad with a two-fold excess of Et3GeLi in THF, gives a 1:2 mixture of: 1,1,2,2-tetra-(trimethylsilyl)-3-trimethylsilyl-3-triethylgermoxy, 4-(1-adamantyl)-trisilacyclobutane (4) and adamantoyladamantyl-carbinol (5). The crystal structure of 4 is described and discussed. It is suggested that the trisilacyclobutane skeleton is formed by a cycloaddition reaction between a silene and a disilene.

引用

页码：123 / 129

页数：7

共 28 条

[11] DUBCHAK IL, 1981, ZH STRUKT KHIM, V22, P156
[12] THE X-RAY CRYSTAL-STRUCTURE OF TETRAMESITYLDISILENE
FINK, MJ
MICHALCZYK, MJ
HALLER, KJ
WEST, R
MICHL, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (18) : 1010 - 1011
[13] FRITZ G, 1981, Z ANORG ALLG CHEM, V473, P59, DOI 10.1002/zaac.19814730207
[14] SYNTHESES AND REACTIONS OF TRIETHYLGERMYLLITHIUM, TRIETHYLGERMYLSODIUM, TRIETHYLGERMYLPOTASSIUM, TRIETHYLGERMYLRUBIDIUM AND TRIETHYLGERMYLCESIUM IN WEAK SOLVATING SOLVENTS
GLADYSHEV, EN
VYAZANKI.NS
FEDOROVA, EA
YUNTILA, LO
RAZUVAEV, GA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 64 (03) : 307 - 314
[15] HETEROSUBSTITUTED CYCLOPOLYSILANES - UNUSUAL STRUCTURES AND A NEW MODEL OF BONDING IN 1,3-DISUBSTITUTED 4-MEMBERED RINGS
GREV, RS
SCHAEFER, HF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (22) : 6577 - 6585
[16] GUSELNIKOV LE, 1989, SOV SCI REV B, V13, P39
[17] Jones R., 1986, ANGEW CHEM, V98, P176
[18] SIGMA-BRIDGED-PI BONDING IN SMALL-RING COMPOUNDS
LIANG, CX
ALLEN, LC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) : 1878 - 1884
[19] CRYSTAL AND MOLECULAR-STRUCTURE OF OCTAPHENYLCYCLOTETRASILANE, C48H40SI4
PARKANYI, L
SASVARI, K
BARTA, I
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAR): : 883 - 887
[20] FORMATION OF ORGANO-SILICON COMPOUNDS .95. CRYSTAL-STRUCTURE OF A HEXADECAMETHYLOCTASILA-DISPIRO[5.1.5.1]TETRADECANE, SI8C22H56
PETERS, K
PETERS, EM
VONSCHNERING, HG
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 502 (07): : 61 - 65

← 1 2 3 →