BROMINATED AND CHLORINATED MANGANESE CHIRAL SCHIFF-BASE COMPLEXES AS EPOXIDATION CATALYSTS

被引：24

作者：

ROBERT, A ^{[1
]}

TSAPARA, A ^{[1
]}

MEUNIER, B ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 85卷 / 01期

关键词：

CHIRAL EPOXIDATION CATALYSTS; EPOXIDATION; HALOGENATED SCHIFF BASE COMPLEXES; MANGANESE; SCHIFF BASES;

D O I：

10.1016/0304-5102(93)87119-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Halogenated manganese(III) chiral Schiff base complexes have been prepared and used as catalysts for enantioselective epoxidation of 1,3-cyclooctadiene and 4-chlorostyrene. Low ee values have been obtained for a terminal olefin like 4-chlorostyrene (10% with 2- and 3-Mn-(S,S) and 34% with 1-Mn-(S,S), Jacobsen's catalyst).

引用

页码：13 / 19

页数：7

共 19 条

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