THERMAL-ENERGY CHARGE-TRANSFER FROM HE+ TO O2 - KINETIC-ENERGY, NATURE, AND REACTIVITY OF THE O+ PRODUCT IONS

被引：38

作者：

MAUCLAIRE, G ^{[1
]}

DERAI, R ^{[1
]}

FENISTEIN, S ^{[1
]}

MARX, R ^{[1
]}

JOHNSEN, R ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT PHYS & ASTRON,PITTSBURGH,PA 15260

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 09期

关键词：

D O I：

10.1063/1.438023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From kinetic energy measurements in an ICR cell, the charge-transfer reaction between thermal He+ and O2 is shown to produce 64% of ground state O+ ions with 1.8 eV kinetic energy, and 36% of electronically excited O+* with 0.3 eV kinetic energy. These O+* react with O2 with a rate constant of 6.5 × 10-10cm3s-1. The nature of this excited state, 2D° or 2P°, is discussed. A resonant, long-distance electron jump explains all the experimental data. © 1979 American Institute of Physics.

引用

页码：4023 / 4026

页数：4