ALDEHYDE INSERTION INTO A PLATINUM HYDRIDE AND SUBSEQUENT NUCLEOPHILIC-ATTACK OF THE ALKOXIDE AT PHOSPHORUS - PLATINUM ALKOXIDE PHOSPHORUS ARYL METATHESIS

被引：45

作者：

VANLEEUWEN, PWNM ^{[1
]}

ROOBEEK, CF ^{[1
]}

ORPEN, AG ^{[1
]}

机构：

[1] UNIV BRISTOL,FACHBEREICH INORGAN CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1021/om00158a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pt(Ph2PO)(Ph2POH)2H (1) was treated with o-(diphenylphosphino)benzaldehyde to give a cyclic platinum alkoxide (2). The latter rearranges to the new product 3 (Scheme I), containing 1-phenyl-3H-2,1-benzoxaphosphole and a phenyl group coordinated to platinum, via a nucleophilic attack at the coordinated phosphorus center by the alkoxy group, followed by a shift of a phenyl group from phosphorus to platinum. The crystal structure of 3 has been determined. © 1990, American Chemical Society. All rights reserved.

引用

页码：2179 / 2181

页数：3

共 30 条

[21] CHELATE-ASSISTED OXIDATIVE ADDITION OF FUNCTIONALIZED PHOSPHINES TO IRIDIUM(I)
LANDVATTER, EF
RAUCHFUSS, TB
[J]. ORGANOMETALLICS, 1982, 1 (03) : 506 - 513
[22] NOVEL REGIOSELECTIVITY AND C-F BOND-CLEAVAGE IN THE REACTIONS OF ALKYLPLATINUM(II) COMPLEXES WITH AMIDE AND ALKOXIDE ANIONS
PARK, S
PONTIERJOHNSON, M
ROUNDHILL, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) : 3101 - 3103
[23] TRANSITION-METAL ACTIVATION OF ALDEHYDES - PLATINUM METAL DERIVATIVES OF "ORTHO-DIPHENYLPHOSPHINOBENZALDEHYDE
RAUCHFUSS, TB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (04) : 1045 - 1047
[24] SCHIEMENZ GP, 1973, LIEBIGS ANN CHEM, V9, P1480
[25] ALKYLCOBALT CARBONYLS .9. ALKOXY-SUBSTITUTED, SILYLOXY-SUBSTITUTED AND HYDROXY-SUBSTITUTED METHYLCOBALT AND ACETYLCOBALT CARBONYLS - REDUCTION OF FORMALDEHYDE TO METHANOL BY HYDRIDOCOBALT TETRACARBONYL
SISAK, A
SAMPARSZERENCSES, E
GALAMB, V
NEMETH, L
UNGVARY, F
PALYI, G
[J]. ORGANOMETALLICS, 1989, 8 (04) : 1096 - 1100
[26] THE FORMATION OF CATALYTICALLY ACTIVE SPECIES BY THE REDUCTION OF PALLADIUM CARBOXYLATE PHOSPHINE SYSTEMS .1. HYDROGENATIONS
SISAK, A
UNGVARY, F
KISS, G
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1983, 18 (02): : 223 - 235
[27] CHARACTERIZATION OF THE INTERMEDIATES IN THE HYDROFORMYLATION REACTION CATALYZED BY PLATINUM DIPHENYLPHOSPHINOUS ACID COMPLEXES
VANLEEUWEN, PWNM
ROOBEEK, CF
FRIJNS, JHG
ORPEN, AG
[J]. ORGANOMETALLICS, 1990, 9 (04) : 1211 - 1222
[28] PLATINUM HYDROFORMYLATION CATALYSTS CONTAINING DIPHENYLPHOSPHINE OXIDE LIGANDS
VANLEEUWEN, PWNM
ROOBEEK, CF
WIFE, RL
FRIJNS, JHG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (01) : 31 - 33
[29] SYNTHESIS AND REACTIVITY OF THE HYDROXYMETHYL COMPLEX OF RHODIUM OCTAETHYLPORPHYRIN
VANVOORHEES, SL
WAYLAND, BB
[J]. ORGANOMETALLICS, 1985, 4 (10) : 1887 - 1888
[30] SYNTHESIS AND REACTIVITY OF STABLE METALLACYCLIC MANGANESE AND RHENIUM ALPHA-HYDROXYALKYL COMPLEXES OF THE FORMULA (CO)4MP(C6H5)2(ORTHO-C6H4CHOH)
VAUGHN, GD
STROUSE, CE
GLADYSZ, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) : 1462 - 1473

← 1 2 3 →