SPECTROSCOPIC INVESTIGATION OF ENERGY-TRANSFER REACTIONS IN BCL3/N2 DISCHARGES

被引：10

作者：

BREITBARTH, FW

机构：

[1] Institute of Physical Chemistry, Friedrich-Schiller-University, Jena, D-O-6900

来源：

PLASMA CHEMISTRY AND PLASMA PROCESSING | 1992年 / 12卷 / 03期

关键词：

NITROGEN PLASMA; BCL3; DISSOCIATION; EMISSION SPECTROSCOPY; ENERGY TRANSFER;

D O I：

10.1007/BF01447025

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In weakly excited low-pressure BCl3/N2 discharges, the emission intensity of the first positive N2 system decreases steeply with increasing BCl3 molar fraction, while the emissions of BCl and atomic boron exhibit narrow maxima at BCl3 molar fractions of 1 and 0.4%, respectively. From the molar fraction dependence of the electron density and of the N2 second positive emission, it is concluded that electron impact excitation is not responsible for the observed BCl and B emissions. An energy transfer from the N2(W) state to BCl(x) species can explain the results.

引用

页码：261 / 274

页数：14

共 13 条

[1]

BREITBARTH FW, 1984, WISS Z F SCHILLER U, V33, P153

[2] ELECTRON-IMPACT EXCITATION OF ELECTRONIC STATES OF N2 .1. DIFFERENTIAL CROSS-SECTIONS AT INCIDENT ENERGIES FROM 10 TO 50 EV [J].