EVOLUTION OF THE SPACE-CHARGE LAYER DURING ELECTROCHEMICAL DEPOSITION WITH CONVECTION

被引：36

作者：

FLEURY, V

KAUFMAN, J

HIBBERT, B

机构：

[1] IBM CORP,DIV RES,ALMADEN RES CTR,SAN JOSE,CA

[2] UNIV NEW S WALES,SCH CHEM,KENSINGTON,NSW 2033,AUSTRALIA

来源：

PHYSICAL REVIEW E | 1993年 / 48卷 / 05期

关键词：

D O I：

10.1103/PhysRevE.48.3831

中图分类号：

O35 [流体力学]; O53 [等离子体物理学];

学科分类号：

070204 ; 080103 ; 080704 ;

摘要：

We study the effect of convection on the concentration profiles in electrolytic cells during electrochemical deposition without a supporting electrolyte. We give theoretical evidence that convection decreases the size of the space charge on the cathodic side during fast electrochemical deposition. This effect may provide a limiting amplitude of the convective motion.

引用

页码：3831 / 3840

页数：10

共 34 条

[21] COPPER ELECTRODEPOSITS IN PAPER SUPPORT [J].

HIBBERT, DB ;

MELROSE, JR .

PHYSICAL REVIEW A, 1988, 38 (02) :1036-1048

[22] MORPHOLOGICAL EVOLUTION IN ZINC ELECTRODEPOSITION [J].

KAHANDA, GLMKS ;

TOMKIEWICZ, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (05) :1497-1502

[23]

KAUFMAN J, UNPUB

[24]

LAM L, 1990, NONLINEAR STRUCTURES

[25] FRACTAL STRUCTURES OF ZINC METAL LEAVES GROWN BY ELECTRODEPOSITION [J].

MATSUSHITA, M ;

SANO, M ;

HAYAKAWA, Y ;

HONJO, H ;

SAWADA, Y .

PHYSICAL REVIEW LETTERS, 1984, 53 (03) :286-289

[26]

MELROSE JR, 1990, PHYS REV LETT, V65, P24

[27]

PON MK, UNPUB

[28]

ROSSO M, IN PRESS ELECTROCHIM

[29] GROWTH VELOCITY OF ELECTROCHEMICAL DEPOSITION AND ITS CONCENTRATION-DEPENDENCE [J].

SAWADA, Y ;

HYOSU, H .

PHYSICA D, 1989, 38 (1-3) :299-303

[30] DENDRITIC AND FRACTAL PATTERNS IN ELECTROLYTIC METAL DEPOSITS [J].

SAWADA, Y ;

DOUGHERTY, A ;

GOLLUB, JP .

PHYSICAL REVIEW LETTERS, 1986, 56 (12) :1260-1263

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