SYNTHESIS AND TRANSFORMATIONS OF METALLOCYCLES .14. STEREOSELECTIVE SYNTHESIS OF TRANS-3,4-DIALKYLTETRAHYDROTHIOPHENES

被引：12

作者：

DZHEMILEV, UM

IBRAGIMOV, AG

AZHGALIEV, MN

MUSLUKHOV, RR

机构：

[1] Ural Branch of the Russian Academy of Sciences, Institute of Organic Chemistry, Ufa, 450054

来源：

RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 02期

关键词：

TRANS-3,4-DISUBSTITUTED TETRAHYDROTHIOPHENES; SYNTHESIS;

D O I：

10.1007/BF00695822

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot stereoselective method was developed for the synthesis of trans-3,4-dialkyltetrahydrothiophenes from alpha-olefins, EtAlCl(2), metallic magnesium, and elementary sulfur (S-8) in the presence of catalytic amounts of Cp(2)ZrCl(2).

引用

页码：255 / 257

页数：3