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MONOMETALLATION OF A DI(AMINOARYL) ETHER INDUCES A SMILES REARRANGEMENT LEADING TO A SODIUM ARYLOXIDE COMPLEX - THE SYNTHESIS AND CRYSTAL-STRUCTURE OF [(MEOCH2CH2)(C6H4NHCH2CH2OME)NC6H4O=NA]2

被引：11
作者：
CRAGGHINE, I
DAVIDSON, MG
KOCIAN, O
KOTTKE, T
MAIR, FS
SNAITH, R
STODDART, JF
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
[2] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND
[3] INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 17期
关键词：
D O I：
10.1039/c39930001355
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound was synthesised by 1 : 1 reaction of sodium hydride with a di(aminoaryl) ether ligand in toluene-hexamethylphosphoramide (HMPA) solution; X-ray crystallography revealed that an in situ Smiles rearrangement of the ligand had taken place to give a dimeric aryloxide sodium complex, which is in stark contrast to previous results obtained by 2 : 1 reaction of Bu(n)Li with the ligand in the absence of HMPA.
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页码：1355 / 1357
页数：3
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