SUPRAMOLECULAR RECEPTORS FOR SAW AND QMB DEVICES - SOLVENT RECOGNITION EVALUATED BY FT-IR SPECTROSCOPY AND BET ADSORPTION ANALYSIS

被引：20

作者：

DICKERT, FL ^{[1
]}

GEIGER, U ^{[1
]}

KEPPLER, M ^{[1
]}

REIF, M ^{[1
]}

BULST, WE ^{[1
]}

KNAUER, U ^{[1
]}

FISCHERAUER, G ^{[1
]}

机构：

[1] SIEMENS AG,CORP RES & DEV,ZFE ST KM1,D-81739 MUNICH,GERMANY

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 1995年 / 26卷 / 1-3期

关键词：

SAW DEVICES; QMB DEVICES; SUPRAMOLECULAR RECEPTORS; FT-IR SPECTROSCOPY; BET ADSORPTION ANALYSIS;

D O I：

10.1016/0925-4005(94)01586-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Sensor effects can be predicted by force field calculations if the formation of host-guest complexes determines the sensor signal. Strong support for this supramolecular recognition is available by BET analysis. This method allows the determination of the number of strong complexing sites in the layer and the corresponding heats of adsorption that are in good agreement with calculated data. Additionally, the host-guest interaction can be pursued by FT-IR spectroscopy using CDCl3 as sensitive probe. These ideas can be used to design rugged functionalized polymeric sensor materials that fulfill the requirements of practical sensoric operation.

引用

页码：199 / 202

页数：4

共 9 条

[1] THE DETECTION OF HALOGENATED HYDROCARBONS VIA HOST GUEST CHEMISTRY - A MASS-SENSITIVE SENSOR STUDY WITH QMB-DEVICES AND SAW-DEVICES
DICKERT, FL
BAUER, PA
[J]. ADVANCED MATERIALS, 1991, 3 (09) : 436 - 438
[2] TETRAAZACYCLOPHANES AS HOST MOLECULES FOR SOLVENT VAPORS - MASS-SENSITIVE DETECTION AND FORCE-FIELD CALCULATIONS
DICKERT, FL
HAUNSCHILD, A
MAUNE, V
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 1993, 12 (03) : 169 - 173
[3] SENSORS FOR ORGANIC-SOLVENT DETECTION IN THE PPM RANGE BASED ON DIOXO[6.1.6.1]PARACYCLOPHANES - FROM MOLECULAR MODELING TO ANALYTE RECOGNITION
DICKERT, FL
HAUNSCHILD, A
REIF, M
BULST, WE
[J]. ADVANCED MATERIALS, 1993, 5 (04) : 277 - 279
[4] SUPRAMOLECULAR DETECTION OF SOLVENT VAPORS WITH QMB AND SAW DEVICES
DICKERT, FL
BRUCKDORFER, T
FEIGL, H
HAUNSCHILD, A
KUSCHOW, V
OBERMEIER, E
BULST, WE
KNAUER, U
MAGES, G
[J]. SENSORS AND ACTUATORS B-CHEMICAL, 1993, 13 (1-3) : 297 - 301
[5] Grate J., 1993, ANAL CHEM, V65, P940
[6] GRATE JW, 1993, ANAL CHEM, V65, P987
[7] SELECTIVE FUNCTIONALIZATION OF HYDROCARBONS .5. THE REGIOSELECTIVITY AND STEREOSELECTIVITY OF RADICAL CHLORINATION OF CYCLOALKANES WITH DIFFERENT HALOGEN CARRIERS AND HOST-GUEST COMPLEXES
SCHNEIDER, HJ
PHILIPPI, K
[J]. CHEMISCHE BERICHTE-RECUEIL, 1984, 117 (10): : 3056 - 3074
[8] ZUR KENNTNIS DER MAKROCYCLISCHEN RINGSYSTEME .2. UBER DIE BIS-[N,N'-ALKYLENBENZIDINE
STETTER, H
ROOS, EE
[J]. CHEMISCHE BERICHTE-RECUEIL, 1955, 88 (09): : 1390 - 1395
[9] NEW WATERSOLUBLE MACROBICYCLIC CAVITIES
WALLON, A
PETERKATALINIC, J
WERNER, U
MULLER, WM
VOGTLE, F
[J]. CHEMISCHE BERICHTE, 1990, 123 (02) : 375 - 379

← 1 →