SYNTHESIS AND REACTIVITIES OF DIAZOALKANE COMPLEXES

被引：103

作者：

MIZOBE, Y ^{[1
]}

ISHII, Y ^{[1
]}

HIDAI, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT CHEM & BIOTECHNOL,TOKYO 113,JAPAN

来源：

COORDINATION CHEMISTRY REVIEWS | 1995年 / 139卷

关键词：

D O I：

10.1016/0010-8545(94)01118-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diazoalkane complexes have been attracting wide interest because of their rich coordination chemistry. Diazoalkane ligands, derived from either free diazoalkanes or other precursors such as coordinated dinitrogen, azines, and hydrazones, display numerous coordination modes acting as pi- and/or sigma-bound terminal, bridging, or chelating ligands to form mono- or multimetallic complexes. The reactivities of coordinated diazoalkanes are largely affected by their coordination modes. The variety of reactivities observed for these coordinated diazoalkanes is quite different from those of free diazoalkanes. In this review are described the synthesis, structures, and reactivities of diazoalkane complexes.

引用

页码：281 / 311

页数：31

共 93 条

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