SYNTHESIS AND REACTIVITIES OF DIAZOALKANE COMPLEXES

被引：103

作者：

MIZOBE, Y ^{[1
]}

ISHII, Y ^{[1
]}

HIDAI, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT CHEM & BIOTECHNOL,TOKYO 113,JAPAN

来源：

COORDINATION CHEMISTRY REVIEWS | 1995年 / 139卷

关键词：

D O I：

10.1016/0010-8545(94)01118-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diazoalkane complexes have been attracting wide interest because of their rich coordination chemistry. Diazoalkane ligands, derived from either free diazoalkanes or other precursors such as coordinated dinitrogen, azines, and hydrazones, display numerous coordination modes acting as pi- and/or sigma-bound terminal, bridging, or chelating ligands to form mono- or multimetallic complexes. The reactivities of coordinated diazoalkanes are largely affected by their coordination modes. The variety of reactivities observed for these coordinated diazoalkanes is quite different from those of free diazoalkanes. In this review are described the synthesis, structures, and reactivities of diazoalkane complexes.

引用

页码：281 / 311

页数：31

共 93 条

[21] SYNTHESIS, STRUCTURE, AND CHEMISTRY OF LIGATING DICHLORODIAZOMETHANE - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [WBR(DPPE)2N2CCL2]+[PF6]- AND [WBR(DPPE)2[N2C(CL)C(CN)2]].CH2CL2
COLQUHOUN, HM
KING, TJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (18) : 879 - 881
[22] THE ORGANIC-CHEMISTRY OF DINITROGEN
COLQUHOUN, HM
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1984, 17 (01) : 23 - 28
[23] DIAZOALKANE ACTIVATION BY IRIDIUM PHOSPHINE COMPOUNDS .2. UNUSUAL PRODUCTS RESULTING FROM N-2 LOSS FROM THE DIBENZOYLDIAZOMETHANE LIGAND - STRUCTURES OF [IRCL(HC(C(O)PH)2)(PC6H4PH2)(PPH3)].1/2C6H5CH3 AND [IRCL((C6H4)C(O)CC(PH)OPPH2)(PPH3)2].C6H5CH3
COWIE, M
MCKEER, IR
LOEB, SJ
GAUTHIER, MD
[J]. ORGANOMETALLICS, 1986, 5 (05) : 860 - 868
[24] DIAZOALKANE ACTIVATION BY IRIDIUM PHOSPHINE COMPOUNDS .1. COMPLEXES CONTAINING THE INTACT DIBENZOYLDIAZOMETHANE LIGAND AND INTERCONVERSION BETWEEN THE ETA-1-N-BOUND AND A CHELATED N,O-BOUND FORM OF THE LIGAND ACCOMPANIED BY HYDRIDE MIGRATION
COWIE, M
LOEB, SJ
MCKEER, IR
[J]. ORGANOMETALLICS, 1986, 5 (05) : 854 - 860
[25] AN UNUSUAL CHANGE IN THE BONDING MODE OF A BRIDGING ALKYLIDENE LIGAND - STRUCTURE OF CP(CO)3MO-MO(CAR-2-PARA-TOLYL)(N2CAR-2-PARA-TOLYL)CP
CURTIS, MD
MESSERLE, L
[J]. ORGANOMETALLICS, 1987, 6 (08) : 1713 - 1717
[26] METAL-METAL MULTIPLE BONDS .18. ADDITION-REACTIONS OF DIAZOALKANES WITH THE MO=MO TRIPLE BOND IN C5H52MO2(CO)4, C5H4ME2MO2(CO)4, C5ME52MO2(CO)4
CURTIS, MD
MESSERLE, L
DERRICO, JJ
BUTLER, WM
HAY, MS
[J]. ORGANOMETALLICS, 1986, 5 (11) : 2283 - 2294
[27] COMPARATIVE-STUDY OF THE REACTIONS OF DIAZOMETHANE WITH MU(3)-IMIDOYL AND MU(3)-BUTYNE TRINUCLEAR CLUSTERS
DAY, M
FREEMAN, W
HARDCASTLE, KI
ISOMAKI, M
KABIR, SE
MCPHILLIPS, T
ROSENBERG, E
SCOTT, LG
WOLF, E
[J]. ORGANOMETALLICS, 1992, 11 (10) : 3376 - 3384
[28] REVERSIBLE CARBON NITROGEN BOND FORMATION IN THE ISOMERIZATION OF TRIOSMIUM COMPOUNDS DERIVED FROM T-BUTYLDIAZOMETHANE (BUTCHN2) - THE X-RAY CRYSTAL-STRUCTURE OF [OS3H2(BUTCH=NNCO)(CO)8(PME2PH)]
DEEMING, AJ
FUCHITA, Y
HARDCASTLE, K
HENRICK, K
MCPARTLIN, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10): : 2259 - 2264
[29] RETENTION OF DINITROGEN IN THE REACTIONS OF SOME DIAZOALKANES WITH A DIRHODIUM COMPLEX - CRYSTAL AND MOLECULAR-STRUCTURES OF (ETA-C5H5)2RH2(CF3C2CF3.CO.N2CRR'), RR'=MEPH AND (T-BU)2
DICKSON, RS
FALLON, GD
GREAVES, BC
SKELTON, BW
WHITE, AH
[J]. INORGANICA CHIMICA ACTA, 1993, 212 (1-2) : 139 - 148
[30] UNUSUAL ALKYNE-ALKYLIDENE COUPLING REACTIONS AT A RHODIUM-RHODIUM BOND - CRYSTAL AND MOLECULAR-STRUCTURE OF THE BRIDGING BUTADIENE COMPLEX (ETA-C5H5)2RH2(MU-CO)(MU-ETA-2-ETA-2-C(CF3)H=C(CF3)CME=CH2)
DICKSON, RS
GREAVES, BC
[J]. ORGANOMETALLICS, 1993, 12 (08) : 3249 - 3256

← 1 2 3 4 5 6 7 8 9 10 →