INTERACTIONS IN BLOCK COPOLYMERS IN SOLUTION - EFFECT OF HETERO-CONTACTS ON SEGMENTAL INTERACTIONS IN BLOCK COPOLYMERS OF POLY(ISOPRENE - STYRENE) IN SOLUTION

被引：14

作者：

URWIN, JR

机构：

[1] Department of Organic Chemistry, University of Adelaide, Adelaide, SA, 5001

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 08期

关键词：

D O I：

10.1071/CH9691649

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binary cluster integrals or excluded volumes for chemically different segment pairs in block copolymers of poly(isoprene: styrene) have been calculated from the equation derived by Froelich and Benoit for a two- sequence block copolymer. Expansion factors have been recalculated assuming a linear relation for [η]θ with respect to composition employing published values for polystyrene and polyisoprene. The results are discussed in relation to possible conformations of block copolymers. © 1969, CSIRO. All rights reserved.

引用

页码：1649 / &

共 14 条

[1] THE MISCIBILITY OF POLYMERS .1. PHASE EQUILIBRIA IN SYSTEMS CONTAINING 2 POLYMERS AND A MUTUAL SOLVENT [J].