THE REACTIONS OF [RU(ETA-6-ARENE)CL2]2 COMPOUNDS WITH A SERIES OF AMINOPYRIDINE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [RU(ETA-6-1,4-MEC6H4CHME2)CL2(NC5H4NH2)] AND [RU(ETA-6-C16H16)CL2(NC5H4NH2)]

被引：22

作者：

ARONSON, R ^{[1
]}

ELSEGOOD, MRJ ^{[1
]}

STEED, JW ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 15期

关键词：

D O I：

10.1016/S0277-5387(00)83792-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the dimers [Ru(eta-6-arene)Cl2]2 (arene = C6H6, 1,4-MeC6H4CHMe2, [2(2)](1,4)C16H16) with a range of aminopyridine ligands have been investigated. These ligands can potentially coordinate to a single metal centre in a monodentate fashion through either pyridyl or amino nitrogen atoms, can chelate a single metal centre, or can bridge across two metal ions. Spectroscopic data collected on 12 compounds is exclusively consistent with monodentate coordination via the pyridyl nitrogen atoms. This mode of coordination has been conclusively established by X-ray structure determinations of the compounds [Ru(eta-6-1,4-MeC6H4CHMe2)Cl2(NC5H4NH2)] and Ru(eta-6-C16H16) Cl2(NC5H4NH2)].

引用

页码：1727 / 1732

页数：6

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