ALKOXIDE PRECURSORS FOR CONTROLLED OXYGEN INCORPORATION DURING METALORGANIC VAPOR-PHASE EPITAXY GAAS AND ALXGA1-XAS GROWTH

被引:23
作者
HUANG, JW
GAINES, DF
KUECH, TF
POTEMSKI, RM
CARDONE, F
机构
[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706
[2] IBM CORP,THOMAS J WATSON RES CTR,YORKTOWN HTS,NY 10598
关键词
ALXGA1-XAS; DEEP LEVELS; DOPING; GROWTH CHEMISTRY; METALORGANIC VAPOR PHASE EPITAXY (MOVPE); OXYGEN;
D O I
10.1007/BF02653353
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Controlled oxygen incorporation in GaAs using Al-O bonding based precursors, dimethyl aluminum methoxide (DMALO) and diethyl aluminum ethoxide (DEALO), is presented in this investigation. A comparison study of oxygen incorporation kinetics between nominally undoped AlxGa1-xAs using trimethyl aluminum and DMALO-doped GaAs suggests that DMALO is one of the most important oxygen-bearing agents responsible for unintentional oxygen incorporation in AlxGa1-xAs. Controlled oxygen doping using DEALO is reported for the first time. Oxygen incorporation behavior, especially on the effect of the V/III ratio, was found to be quite different from the case of DMALO, mainly due to the differences between methyl- and ethyl-based growth chemistries. Physical, electrical, and optical properties of these oxygen-doped GaAs are also reported.
引用
收藏
页码:659 / 667
页数:9
相关论文
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