CYCLODEXTRIN-MODIFIED MICELLAR ELECTROKINETIC CHROMATOGRAPHY - SEPARATION OF HYDROPHOBIC AND ENANTIOMERIC COMPOUNDS

被引：212

作者：

TERABE, S ^{[1
]}

MIYASHITA, Y ^{[1
]}

ISHIHAMA, Y ^{[1
]}

SHIBATA, O ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

JOURNAL OF CHROMATOGRAPHY | 1993年 / 636卷 / 01期

关键词：

D O I：

10.1016/0021-9673(93)80055-D

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cyclodextrin (CD)-modified micellar electrokinetic chromatography was applied to the separation of closely related aromatic compounds and enantiomeric separations using CD together with sodium dodecyl sulphate (SDS). Nine isomeric dimethylnaphthalenes, which were not resolved at all with an SDS solution, were successfully separated with gamma-CD and SDS. Sixteen polycyclic aromatic hydrocarbons were also almost completely separated. Dansylated (Dns)-DL-amino acids were optically resolved with combinations of SDS and beta- or gamma-CD and sodium taurodeoxycholate and gamma-CD. Maltoheptaose was employed instead of CD, giving partial resolution of some DnS-DL-amino acids.

引用

页码：47 / 55

页数：9

共 21 条

[1] EXTENSION OF ELUTION RANGE IN MICELLAR ELECTROKINETIC CAPILLARY CHROMATOGRAPHY [J].

BALCHUNAS, AT ;

SEPANIAK, MJ .

ANALYTICAL CHEMISTRY, 1987, 59 (10) :1466-1470

[2] BILE-SALT SURFACTANTS IN MICELLAR ELECTROKINETIC CAPILLARY CHROMATOGRAPHY - APPLICATION TO HYDROPHOBIC MOLECULE SEPARATIONS [J].

COLE, RO ;

SEPANIAK, MJ ;

HINZE, WL ;

GORSE, J ;

OLDIGES, K .

JOURNAL OF CHROMATOGRAPHY, 1991, 557 (1-2) :113-123

[3]

COLE RO, 1990, HRC-J HIGH RES CHROM, V13, P579

[4] OPTIMIZATION OF MICELLAR ELECTROKINETIC CHROMATOGRAPHY [J].

FOLEY, JP .

ANALYTICAL CHEMISTRY, 1990, 62 (13) :1302-1308

[5] TOPOGRAPHY OF CYCLODEXTRIN INCLUSION COMPLEXES .3. CRYSTAL AND MOLECULAR-STRUCTURE OF CYCLOHEXAAMYLOSE HEXAHYDRATE, (H2O)2 INCLUSION COMPLEX [J].

MANOR, PC ;

SAENGER, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (11) :3630-3639

[6]

MIYASHITA Y, 1990, P ACE SYSTEM 2000 AP

[7] SEPARATION AND DETERMINATION OF LIPOPHILIC CORTICOSTEROIDS AND BENZOTHIAZEPIN ANALOGS BY MICELLAR ELECTROKINETIC CHROMATOGRAPHY USING BILE-SALTS [J].

NISHI, H ;

FUKUYAMA, T ;

MATSUO, M ;

TERABE, S .

JOURNAL OF CHROMATOGRAPHY, 1990, 513 :279-295

[8] SEPARATION OF CORTICOSTEROIDS AND AROMATIC-HYDROCARBONS BY CYCLODEXTRIN-MODIFIED MICELLAR ELECTROKINETIC CHROMATOGRAPHY [J].

NISHI, H ;

MATSUO, M .

JOURNAL OF LIQUID CHROMATOGRAPHY, 1991, 14 (05) :973-986

[9] CHIRAL SEPARATION OF TRIMETOQUINOL HYDROCHLORIDE AND RELATED-COMPOUNDS BY MICELLAR ELECTROKINETIC CHROMATOGRAPHY USING SODIUM TAURODEOXYCHOLATE SOLUTIONS AND APPLICATION TO OPTICAL PURITY DETERMINATION [J].

NISHI, H ;

FUKUYAMA, T ;

MATSUO, M ;

TERABE, S .

ANALYTICA CHIMICA ACTA, 1990, 236 (02) :281-286

[10] CHIRAL SEPARATION BY CYCLODEXTRIN-MODIFIED MICELLAR ELECTROKINETIC CHROMATOGRAPHY [J].

NISHI, H ;

FUKUYAMA, T ;

TERABE, S .

JOURNAL OF CHROMATOGRAPHY, 1991, 553 (1-2) :503-516

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