THERMOELECTRIC EFFECTS IN ELECTROCHEMICAL SYSTEMS - NONCONVENTIONAL THERMOGALVANIC CELLS

被引：70

作者：

KUZMINSKII, YV

ZASUKHA, VA

KUZMINSKAYA, GY

机构：

[1] Research and Engineering Centre Tekhnoelektrokhim, Institute of General and Inorganic Chemistry, Ukrainian National Academy of Sciences, 252680 Kiev 142

来源：

JOURNAL OF POWER SOURCES | 1994年 / 52卷 / 02期

关键词：

ELECTROCHEMICAL SYSTEMS; THERMOGALVANIC CELLS;

D O I：

10.1016/0378-7753(94)02015-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the present study, the possibility of using electrochemical systems for solving the problems of direct thermoelectric conversion is considered for a number of nonconventional electrochemical couples: 'inert' electrode/macrocyclic complex with the central coordinated metal ion in different oxidation states (aqueous, aprotic organic electrolyte), 'inert' electrode/metal ion in different oxidation states (molten salt), lithium intercalate/lithium-containing aprotic organic electrolyte, semiconductor/molten salt. A comparative analysis of data on the main criteria of thermoelectric ability (Seebeck coefficient, efficiency factor, Z-factor, efficiency, etc.) confirmed that it is possible in principle to use the electrochemical systems studied in direct thermoelectric conversion devices.

引用

页码：231 / 242

页数：12

共 53 条

[11]

GORODYSKII AV, 1976, Patent No. 545836

[12]

HAASE R, 1967, THERMODYNAMIC IRREVE

[13] ELECTRONIC PROPERTIES AND STEREOCHEMISTRY OF COPPER(2) ION .6. BIS(BIPYRIDYL)COPPER(2) COMPLEXES [J].

HATHAWAY, BJ ;

PROCTER, IM ;

SLADE, RC ;

TOMLINSON, AA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (15) :2219-+

[14]

Hoffman Gy, 1971, C APPLIED PHYSICAL C, P661

[15]

Ioffe A. F., 1960, POLUPROVODNIKOVYE TE

[16]

Iordanishvii Y. K., 1968, THERMOELECTRIC POWER

[17] THERMAL-ANALYSIS OF ELECTROCHEMICAL REACTIONS .2. THE NON-STATIONARY TEMPERATURE WAVE METHOD - A METHOD FOR THE DETERMINATION OF PELTIER HEATS AT THE ELECTRODE MOLTEN ELECTROLYTE INTERFACE [J].

KUZMINSKII, YV ;

ANDRIIKO, AA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 252 (01) :39-52

[18] THERMAL-ANALYSIS OF ELECTROCHEMICAL REACTIONS .1. KINETIC METHOD OF DETERMINING PELTIER HEATS [J].

KUZMINSKII, YV ;

GORODYSKII, AV .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 252 (01) :21-37

[19]

KUZMINSKII YV, 1986, UKR KHIM ZH, V52, P1055

[20]

KUZMINSKII YV, 1987, 8TH INT S SOL SOL SO, P279

← 1 2 3 4 5 6 →