MOLECULAR-STRUCTURE OF BROMINE PENTAFLUORIDE - JOINT ANALYSIS OF GAS ELECTRON-DIFFRACTION DATA AND MICROWAVE ROTATIONAL CONSTANTS

被引：13

作者：

HEENAN, RK

ROBIETTE, AG

机构：

[1] Department of Chemistry, University of Reading, Reading

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1979年 / 54卷 / JUL期

关键词：

D O I：

10.1016/0022-2860(79)80062-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The zero-point average structure of BrF5 has been determined by least-squares refinement to gas electron diffraction data and rotational constants obtained from microwave spectroscopy. The preferred values of the structural parameters, with 2σ error estimates in parentheses, are rav(BrF, mean) = 1.753(2) Å, Δrav(BrFeq - BrFax) = 0.069(6) Å, and ∠ FaxBrFeq = 85.1(4)°. © 1979.

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页码：135 / 144

页数：10

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