SYNTHESIS AND CRYSTAL-STRUCTURE OF PH(3)LN(THF)(3) (LN=ER, TM)

被引：42

作者：

BOCHKAREV, LN

STEPANTSEVA, TA

ZAKHAROV, LN

FUKIN, GK

YANOVSKY, AI

STRUCHKOV, YT

机构：

[1] RUSSIAN ACAD SCI,INST ORGANOMETALL CHEM,NIZHNII NOVGOROD 603600,RUSSIA

[2] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 05期

关键词：

D O I：

10.1021/om00005a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triphenyllanthanoids Ph(3)Ln(THF)(3) (Ln = Er (1), Tm (2)) were synthesized in THF by reaction of metallic lanthanoids with Ph(2)Hg or Ph(3)Bi in the presence of catalytic amounts of LnI(3). The X-ray diffraction studies of 1 and 2 have shown that these species represent monomeric complexes with a distorted fac-octahedral arrangement of ligands around the Ln atom.

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页码：2127 / 2129

页数：3

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