EXTRACTION KINETICS OF "INDIUM-TRIS(DIETHYLDITHIOCARBAMATE)

被引：7

作者：

WYTTENBACH, A

BAJO, S

机构：

[1] Swiss Federal Institute for Reactor Research

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 06期

关键词：

D O I：

10.1016/0022-1902(79)80282-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The extraction of In(III) from acid aqueous solutions containing Cl- as In-tris(diethyldithiocarbamate) into CHCl3 has been studied. Cd-bis(diethyldithiocarbamate) was used to maintain a small but constant ligand concentration in the aqueous phase. The rate of extraction has been shown to be controlled by two reactions in the aqueous phase, one involving the diethyldithiocarbamic acid, the other the diethyldithiocarbamate anion. The reacting In(III) species is InCl2+. © 1979.

引用

页码：867 / 870

页数：4

共 17 条

[11]

FOMIN VV, 1971, RUSS J INORG CHEM, V16, P1182

[12]

FOMIN VV, 1975, SOV RADIOCHEM, V17, P649

[13] KINETIC STUDIES OF SOLVENT-EXTRACTION OF METAL-COMPLEXES .2. RATE OF EXTRACTION OF IRON(III) WITH THENOYLTRIFLUOROACETONE INTO CARBON-TETRACHLORIDE [J].

SEKINE, T ;

YUMIKURA, J ;

KOMATSU, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (08) :2356-2360

[14]

SPIVAKOV BY, 1969, J ANAL CHEM USSR, V24, P1437

[15]

VANDERWEIDEN CH, 1975, RCN221 REP

[16]

VINOKUROVA OB, 1976, J ANAL CHEM-USSR+, V31, P871

[17] EXTRACTIONS WITH METAL-DITHIOCARBAMATES AS REAGENTS [J].

WYTTENBACH, A ;

BAJO, S .

ANALYTICAL CHEMISTRY, 1975, 47 (11) :1813-1817

← 1 2 →