IONIC INTERACTIONS IN SOLUTIONS .4. CONDUCTANCE THEORY OF BINARY ELECTROLYTES FOR HAMILTONIAN MODELS

被引：20

作者：

JUSTICE, JC ^{[1
]}

EBELING, W ^{[1
]}

机构：

[1] UNIV ROSTOCK, SEKT PHYS, DDR-25 ROSTOCK 1, GER DEM REP

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1979年 / 8卷 / 11期

关键词：

binary electrolytes; Conductance; effects; feedback or echo effect; Gurney cosphere; Hamiltonian models; strong coupling approximation;

D O I：

10.1007/BF00648580

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From the basic equations for the pair distribution function in nonequilibrium, solution methods are elaborated. It is verified that the distribution functions depend on conductance coefficients, which lead to feedback loop or echo effects. For explicit calculation the strong-coupling approximation for distances smaller than the Bjerrum distance proves to be practical and efficient. It can be applied to any Hamiltonian models for the system without complicated mathematics. A method of deriving information concerning the Gurney cosphere overlap effects is presented. © 1979 Plenum Publishing Corporation.

引用

页码：809 / 833

页数：25

共 33 条

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