ORGANOMETALLIC REAGENTS IN ORGANIC-SYNTHESIS .4. SYNTHESIS OF ORTHOTRITHIOFORMATES AND RELATED COMPOUNDS - CARBANION FORMATION AND EVALUATION FOR 1,4 ADDITION-REACTIONS WITH ALPHA,BETA-UNSATURATED KETONES

被引：17

作者：

SMITH, RAJ

LAL, AR

机构：

[1] Chemistry Department, University of Otago, Dunedin

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1071/CH9790353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of potential α-sulfur-substituted carbanion precursors (2a-h) are reported and the results of their subsequent reactions with strong bases are presented. The relatively stable carbanions (3a-d) were made to react with a variety of α, β-unsaturated ketones and the yields of 1, 4 and 1, 2 addition products were determined. © 1979, CSIRO. All rights reserved.

引用

页码：353 / 360

页数：8

共 33 条

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