IRON CATALYZED INSERTION OF SULFUR INTO THE NONACTIVATED C-H BOND

被引：14

作者：

BALAVOINE, G ^{[1
]}

BARTON, DHR ^{[1
]}

GREF, A ^{[1
]}

LELLOUCHE, I ^{[1
]}

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

来源：

TETRAHEDRON | 1992年 / 48卷 / 10期

关键词：

D O I：

10.1016/S0040-4020(01)88512-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of various sulfur reagents (S8, H2S, Na2S, NaHS) with cyclohexane under Gif(III), GoAggII and GoAggIII conditions affords the usual oxidation products in competition with cyclohexyl di- and poly-sulfide formation. Other cyclic hydrocarbons behave similarly. The sulfation reactions are considered to be biomimetic for the enzymes isopenicillin N synthase and biotin synthase.

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页码：1883 / 1894

页数：12

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