SYNTHESIS AND CRYSTAL-STRUCTURE OF THE 6-COORDINATE RUTHENIUM NITROSYL COMPLEX [(ETA-5-C5H5)RU(PPH3)(NO)(CL)]PF6

被引：19

作者：

CONROYLEWIS, FM ^{[1
]}

REDHOUSE, AD ^{[1
]}

SIMPSON, SJ ^{[1
]}

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 399卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85495-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [(eta-5-C5H5)Ru(PPh3)2Cl] (1) with sodium nitrite in hot acidified ethanol followed by anion exchange gave the red crystalline solid [(eta-5-C5H5)Ru(PPh3)(NO)(Cl]PF6 (2) in good yield. Compound 2 has been crystallographically characterised and shows a large interligand angle at ruthenium between the chloride and nitrosyl ligands. The dication {[(eta-5-C5H5)Ru(PPh3)(CN(t)Bu)(NO)][BF4]2} (4) has been prepared from [(eta-5-C5H5)Ru(PPh3)(CN(t)Bu)(Cl] (3) and nitrosonium tetrafluoroborate.

引用

页码：307 / 315

页数：9

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