HELICAL GROUP-12 COORDINATION - THE X-RAY CRYSTAL-STRUCTURE OF A 5-CO-ORDINATE ZINC(II) COMPLEX

被引：15

作者：

ADATIA, T

BEYNEK, N

MURPHY, BP

机构：

[1] MANCHESTER METROPOLITAN UNIV,DEPT CHEM,MANCHESTER M1 5GD,LANCS,ENGLAND

[2] UNIV N LONDON,SCH CHEM,LONDON N7 8DB,ENGLAND

[3] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

POLYHEDRON | 1995年 / 14卷 / 02期

关键词：

D O I：

10.1016/0277-5387(94)00402-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The templated diimine-containing complexes, [M(SpyNpy(2))](ClO4)(2).0.5H(2)O {where M = Zn-II, Cd-II or Hg-II}, exhibit chirality in solution (NMR) which is consistent with, and may be diagnostic of, a helical coordination array in these complexes as verified by the X-ray crystal structure of an enantiomer of the zinc(II) derivative.

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页码：335 / 338

页数：4

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