MACROCYCLIC HELICATES - COMPLEXES OF A 34-MEMBERED SCHIFF-BASE LIGAND

被引：50

作者：

FENTON, DE

MATTHEWS, RW

MCPARTLIN, M

MURPHY, BP

SCOWEN, IJ

TASKER, PA

机构：

[1] UNIV N LONDON, SCH APPL CHEM, LONDON N7 8DB, ENGLAND

[2] UNIV SHEFFIELD, DEPT CHEM, SHEFFIELD S3 7HF, S YORKSHIRE, ENGLAND

[3] ZENECA SPECIAL, MANCHESTER M9 3DA, LANCS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A unique double helical macrocyclic configuration of a new 34-membered Schiff-base macrocycle results from convergence of its two pyridine-2,6-diyldiimine units for meridional coordination of divalent metal ions; X-ray structure analysis establishes the cobalt(II), nickel(II) and zinc(II) complexes as the first structurally characterised macrocyclic helicates.

引用

收藏

页码：1391 / 1392

页数：2

相关论文

共 23 条

[1] COPPER(I) AND SILVER(I) HOMOMETALLIC COMPLEXES OF NEW BIS(2,2'-BIPYRIDINE) LIGANDS [J].

BEER, PD ;

WHEELER, JW ;

MOORE, CP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (18) :2667-2673

[2] PRECURSOR CATENAND COMPLEXES - SYNTHESIS, STRUCTURE, AND ELECTROCHEMISTRY OF BIS(2,6-DI-IMINOPYRIDYL) COMPLEXES OF NICKEL(II) - THE SINGLE-CRYSTAL X-RAY STRUCTURE OF [NIL42][BF4]2 [J].

BLAKE, AJ ;

LAVERY, AJ ;

HYDE, TI ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (05) :965-970

[3] AROMATIC-AROMATIC INTERACTION - A MECHANISM OF PROTEIN-STRUCTURE STABILIZATION [J].

BURLEY, SK ;

PETSKO, GA .

SCIENCE, 1985, 229 (4708) :23-28

[4] SPONTANEOUS SELF-ASSEMBLY OF A DINICKEL(II) DOUBLE HELICATE CONTAINING A 1,3-BENZENEDIYL SPACER GROUP [J].

CONSTABLE, EC ;

HANNON, MJ ;

TOCHER, DA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (02) :230-232

[5] CHEMISTRY - A NEW TWIST TO SELF-ASSEMBLY [J].

CONSTABLE, EC .

NATURE, 1990, 346 (6282) :314-315

[6] THE 1ST STRUCTURALLY CHARACTERIZED HETERODINUCLEAR DOUBLE-HELICATE COMPLEX [J].

CONSTABLE, EC ;

EDWARDS, AJ ;

RAITHBY, PR ;

WALKER, JV .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (10) :1465-1467

[7] THE CRYSTAL-STRUCTURES OF IRON(II) AND COBALT(II) COMPLEXES OF A 30-MEMBERED MACROCYCLIC LIGAND - OBSERVATION OF JAHN-TELLER DISTORTION IN A 6-COORDINATE LOW-SPIN COBALT(II) COMPLEX [J].

DREW, MGB ;

MCCANN, M ;

NELSON, SM .

INORGANICA CHIMICA ACTA-ARTICLES, 1980, 41 (02) :213-219

[8] THE NATURE OF PI-PI INTERACTIONS [J].

HUNTER, CA ;

SANDERS, JKM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5525-5534

[9] ARENE ARENE INTERACTIONS - ELECTROSTATIC OR CHARGE-TRANSFER [J].

HUNTER, CA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (11) :1584-1586

[10] A STRONGLY BINDING, HELICALLY CHIRAL LIGAND SYSTEM [J].

JUDICE, JK ;

KEIPERT, SJ ;

CRAM, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (17) :1323-1325