MACROCYCLIC HELICATES - COMPLEXES OF A 34-MEMBERED SCHIFF-BASE LIGAND

被引：50

作者：

FENTON, DE

MATTHEWS, RW

MCPARTLIN, M

MURPHY, BP

SCOWEN, IJ

TASKER, PA

机构：

[1] UNIV N LONDON, SCH APPL CHEM, LONDON N7 8DB, ENGLAND

[2] UNIV SHEFFIELD, DEPT CHEM, SHEFFIELD S3 7HF, S YORKSHIRE, ENGLAND

[3] ZENECA SPECIAL, MANCHESTER M9 3DA, LANCS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期

关键词：

D O I：

10.1039/c39940001391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A unique double helical macrocyclic configuration of a new 34-membered Schiff-base macrocycle results from convergence of its two pyridine-2,6-diyldiimine units for meridional coordination of divalent metal ions; X-ray structure analysis establishes the cobalt(II), nickel(II) and zinc(II) complexes as the first structurally characterised macrocyclic helicates.

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页码：1391 / 1392

页数：2

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