MOLECULAR-WEIGHT OF POLYANILINE SYNTHESIZED BY OXIDATION OF ANILINE WITH AMMONIUM PERSULFATE AND WITH FERRIC-CHLORIDE

被引：19

作者：

DAVIED, S ^{[1
]}

NICOLAU, YF ^{[1
]}

MELIS, F ^{[1
]}

REVILLON, A ^{[1
]}

机构：

[1] CNRS,MAT ORGAN PROPRIETES SPECIF LAB,F-69390 VERNAISON,FRANCE

来源：

SYNTHETIC METALS | 1995年 / 69卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02385-C

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The results of molecular weight (MW) determinations by GPC on polyaniline (PAn) (as leucoemeraldine base (LEE)) synthesized by oxidation of aniline (An) with ammonium persulfate (AP) and with ferric chloride (FC) are presented together with dynamic light scattering (DLS) and viscosity measurements. After extraction with acetonitrile (AN) and tetrahydrofuran (THF), PAn shows a unimodal MW distribution. The Mn and Mw of PAn synthesised with AP and FC are: 9,900, 50,700 and 13,500, 55,300, respectively. The intensity-weighted particle size distribution (PSDI) determined by DLS in LEE solutions is also unimodal. The mean diameter of the LEE macromolecules is 5 and 7 nm for PAn synthesised with AP and FC, respectively.

引用

页码：125 / 126

页数：2

共 14 条

[1] A COMPARISON OF THE MOLECULAR-WEIGHTS OF POLYANILINE SAMPLES OBTAINED FROM GEL-PERMEATION CHROMATOGRAPHY AND SOLID-STATE N-15 NMR-SPECTROSCOPY [J].

ADAMS, PN ;

APPERLEY, DC ;

MONKMAN, AP .

POLYMER, 1993, 34 (02) :328-332

[2] INFLUENCE OF CHEMICAL POLYMERIZATION CONDITIONS ON THE PROPERTIES OF POLYANILINE [J].

CAO, Y ;

ANDREATTA, A ;

HEEGER, AJ ;

SMITH, P .

POLYMER, 1989, 30 (12) :2305-2311

[3]

GENIES E, 1989, SYNTHETIC MET, V28, pC647, DOI 10.1016/0379-6779(89)90585-7

[4] THE MOLECULAR-WEIGHT OF POLYANILINE BY LIGHT-SCATTERING AND GEL-PERMEATION CHROMATOGRAPHY [J].

HSU, CH ;

PEACOCK, PM ;

FLIPPEN, RB ;

MANOHAR, SK ;

MACDIARMID, AG .

SYNTHETIC METALS, 1993, 60 (03) :233-237

[5] POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].

HUANG, WS ;

HUMPHREY, BD ;

MACDIARMID, AG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&

[6]

MacDiarmid A. G., 1987, Conducting Polymers. Special Applications. Proceedings of the Workshop, P105

[7]

MACDIARMID AG, 1991, POLYM MAT SCI ENG, V64, P254

[8] POLYANILINE - PERNIGRANILINE, AN ISOLABLE INTERMEDIATE IN THE CONVENTIONAL CHEMICAL SYNTHESIS OF EMERALDINE [J].

MANOHAR, SK ;

MACDIARMID, AG ;

EPSTEIN, AJ .

SYNTHETIC METALS, 1991, 41 (1-2) :711-714

[9]

TANG X, 1988, MAKROMOL CHEM-RAPID, V9, P829

[10] A STUDY OF LEUCOEMERALDINE AND THE EFFECT OF REDOX REACTIONS ON THE MOLECULAR-WEIGHT OF CHEMICALLY PREPARED POLYANILINE [J].

WEI, Y ;

HSUEH, KF ;

JANG, GW .

MACROMOLECULES, 1994, 27 (02) :518-525

← 1 2 →