A FACILE SYNTHESIS OF STEROIDAL DELTA(4)-3-KETONES USING PYRIDINIUM CHLOROCHROMATE (PCC)

被引：10

作者：

PARISH, EJ

HONDA, H

机构：

[1] Department of Chemistry, Auburn University, AL

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 08期

关键词：

D O I：

10.1080/00397919008052824

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pyridinium chlorochromate(PCC), in refluxing benzene, has been found to be an effective and convenient reagent for the oxidation and concomitant isomerization of steroidal Δ5-3β-alcohols to the corresponding Δ-3-ketones in high yield. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

引用

页码：1167 / 1174

页数：8

共 26 条

[1] ORGANOBORANES FOR SYNTHESIS .4. OXIDATION OF ORGANOBORANES WITH PYRIDINIUM CHLOROCHROMATE - A DIRECT SYNTHESIS OF ALDEHYDES FROM TERMINAL ALKENES VIA HYDROBORATION [J].