KINETIC-THEORY OF DENSE FLUIDS .2. GENERALIZED CHAPMAN-ENSKOG SOLUTION

被引:12
作者
EU, BC
机构
[1] Department of Chemistry, McGill University, Montreal
关键词
D O I
10.1016/0003-4916(79)90240-9
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In the second paper of this series we solve the kinetic equation proposed in the previous paper by a method following the spirit of Chapman and Enskog (generalized Chapman-Enskog method). The zeroth-order solution to the kinetic equation leads to the Euler equations in hydrodynamics for real fluids, and the first-order solution to the Navier-Stokes equations for real fluids. General formulas for transport coefficients such as viscosity and heat-conductivity coefficients are obtained for dense fluids, which are given in terms of time-correlation functions of fluxes conjugate to the thermodynamic forces. The results have the same formal structures as the time-correlation functions in linear response theory except for the collision operator appearing in place of the Liouville operator in the evolution operator for the system. © 1979.
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页码:230 / 245
页数:16
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