A NEW, SIMPLE, EFFICIENT ELECTROSYNTHESIS OF FUNCTIONALIZED BENZYLIC ZINC SPECIES AND THEIR REACTIVITY TOWARD AROMATIC-ALDEHYDES

被引：9

作者：

GOSMINI, C ^{[1
]}

ROLLIN, Y ^{[1
]}

GEBEHENNE, C ^{[1
]}

LOJOU, E ^{[1
]}

RATOVELOMANANA, V ^{[1
]}

PERICHON, J ^{[1
]}

机构：

[1] CNRS,ELECTROCHIM CATALYSE & SYNTH ORGAN LAB,F-94320 THIAIS,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(00)77267-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various stable substituted benzylic zincs are formed in acetonitrile upon reaction of the bromide derivatives, in good yields, using a catalytic electrogenerated zinc species associated with massive zinc. In the presence of chloronimethylsilane, these organozincs react instantaneously with functionalized aromatic aldehydes.

引用

页码：5637 / 5640

页数：4

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