UNIMOLECULAR DISSOCIATION IN THE REGULAR REGIME

被引：3

作者：

YURTSEVER, E ^{[1
]}

GUNAY, H ^{[1
]}

UZER, T ^{[1
]}

机构：

[1] GEORGIA INST TECHNOL,SCH PHYS,ATLANTA,GA 30332

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 02期

关键词：

D O I：

10.1063/1.465411

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The unimolecular dissociation of a model triatomic molecule is analyzed. The model, which is loosely based on the radical HO2, shows mostly regular dynamical behavior although it has enough energy to dissociate. By analyzing the progress towards dissociation, we find that dissociation takes place due to concerted and correlated motions as in the Slater theory of unimolecular reactions rather than the steady accumulation of energy in the dissociative mode.

引用

页码：1135 / 1144

页数：10

共 22 条

[21] THE DYNAMICS OF A QUANTAL RESERVOIR COUPLED TO CLASSICAL MODES - A MIXED-MODE APPROACH TO DISSOCIATING MOLECULES
YURTSEVER, E
UZER, T
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1992, 96 (07): : 906 - 913
[22] QUANTUM-CLASSICAL MIXED-MODE ANALYSIS OF NONLINEARLY COUPLED OSCILLATORS - A TIME-DEPENDENT SELF-CONSISTENT-FIELD APPROACH
YURTSEVER, E
BRICKMANN, J
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1992, 96 (02): : 142 - 146

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