EFFECT OF TEMPERATURE ON THE STRUCTURE OF GASEOUS MOLECULES .4. MOLECULAR-STRUCTURE AND BARRIER TO INTERNAL-ROTATION FOR DIBORON TETRABROMIDE

被引：40

作者：

DANIELSON, DD ^{[1
]}

HEDBERG, K ^{[1
]}

机构：

[1] OREGON STATE UNIV,DEPT CHEM,CORVALLIS,OR 97331

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 12期

关键词：

D O I：

10.1021/ja00506a011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular structure of B2 Br4 has been investigated by electron diffraction at nozzle temperatures of 23, 90, 150, and 305 °C. The molecule has a staggered equilibrium conformation (symmetry D2d), with the following distances (ra), angles, and root mean square amplitudes of vibration at room temperature:. © 1979, American Chemical Society. All rights reserved.

引用

页码：3199 / 3203

页数：5