VIBRATIONAL SPECTROSCOPIC STUDY OF NICKEL (II) FORMATE, NI(HCO2)2, AND ITS AQUEOUS-SOLUTION

被引：13

作者：

EDWARDS, HGM

KNOWLES, A

机构：

[1] Chemistry and Chemical Technology, University of Bradford, Bradford

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 268卷 / 1-3期

关键词：

D O I：

10.1016/0022-2860(92)85056-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A vibrational spectroscopic study of nickel (II) formate and its aqueous solution has been made. The vibrations characteristic of a formato-nickel complex have been assigned and it is concluded that the species Ni(HCO2) + (HCO2)- exists in the solid state, with monodentate ligand-to-metal bonding. The Raman spectrum of an aqueous solution of nickel (II) formate indicates that complete dissociation of the formato-nickel (II) species occurs to formate ions and nickel (II) hexa-aquo ions. Comparisons are made with other nickel (II) carboxylates.

引用

页码：13 / 22

页数：10

共 12 条

[1]

BERGER J, 1971, COMPT RENDU ACAD S B, P273

[2]

BICKELY RI, 1990, 12TH P INT C RAM SPE, P802

[3] SYNTHESIS AND VIBRATIONAL SPECTROSCOPIC CHARACTERIZATION OF NICKEL (II) PROPIONATE TETRAHYDRATE, NI(CH3CH2COO)2.4H2O, AND ITS AQUEOUS-SOLUTION [J].