CATALYTIC, DIASTEREOSELECTIVE ALDOL REACTIONS USING TITANIUM(IV) HALIDES

被引：30

作者：

MAHRWALD, R

机构：

[1] Fachbereich Chemie der Humboldt-Universität Berlin, Berlin, D-10115

来源：

CHEMISCHE BERICHTE | 1995年 / 128卷 / 09期

关键词：

ALDOL REACTION; STEREOSELECTIVITY; CATALYTIC AMOUNTS OF TITANIUM(IV) HALOGENIDES;

D O I：

10.1002/cber.19951280911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aldol reaction in the presence of titanium halides is described. Good yields of aldols 10-17 were obtained even with only catalytic amounts of titanium tetrafluoride. The reactions were carried out in the absence of a base.

引用

页码：919 / 921

页数：3

共 24 条

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REETZ, MT
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[24] ZIRCONIUM ENOLATES AS A NEW ERYTHRO-SELECTIVE ALDOL CONDENSATION REAGENT
YAMAMOTO, Y
MARUYAMA, K
[J]. TETRAHEDRON LETTERS, 1980, 21 (48) : 4607 - 4610

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