SELECTIVE HALOGENATION AT PRIMARY POSITIONS OF CYCLOMALTOOLIGOSACCHARIDES AND A SYNTHESIS OF PER-3,6-ANHYDRO CYCLOMALTOOLIGOSACCHARIDES

被引：234

作者：

GADELLE, A ^{[1
]}

DEFAYE, J ^{[1
]}

机构：

[1] CEN,CNRS,F-38041 GRENOBLE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

6A; 6X; 6Y-TRI-O-SULFONYLATED BETA-CYCLODEXTRIN; STRUCTURAL DETERMINATION; ENZYMATIC-HYDROLYSIS; HYDROXYL-GROUPS; 6X-DI-OMICRON-(PARA-TOSYL)-GAMMA-CYCLODEXTRINS; 3A; 6A-PARA3X; 6X-DIANHYDRO-GAMMA-CYCLODEXTRINS;

D O I：

10.1002/anie.199100781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cyclodextrin derivatives 2, which contain glucopyranose units in C1(4) conformation, were obtained via the 6-iodo compounds 1. The synthesis of 1 was accomplished by reaction of unsubstituted sugars with Vilsmeier-type reagents (see also following communication).

引用

页码：78 / 80

页数：3

共 18 条

[1] SYNTHESIS AND CHARACTERIZATION OF PER-3,6-ANHYDRO CYCLODEXTRINS
ASHTON, PR
ELLWOOD, P
STATON, I
STODDART, JF
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01): : 80 - 81
[2] ASHTON PR, 1991, ANGEW CHEM, V103, P96
[3] C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF MONOSACCHARIDES
BOCK, K
PEDERSEN, C
[J]. ADVANCES IN CARBOHYDRATE CHEMISTRY AND BIOCHEMISTRY, 1983, 41 : 27 - 66
[4] CYCLODEXTRIN CHEMISTRY - SELECTIVE MODIFICATION OF ALL PRIMARY HYDROXYL-GROUPS OF ALPHA-CYCLODEXTRINS AND BETA-CYCLODEXTRINS
BOGER, J
CORCORAN, RJ
LEHN, JM
[J]. HELVETICA CHIMICA ACTA, 1978, 61 (06) : 2190 - 2218
[5] CASTRO B, 1972, TETRAHEDRON LETT, P5001
[6] INCLUSION COMPOUNDS .20. OPTICAL ROTARY DISPERSION SPECTRA AND CONFORMATION OF GLUCOSE UNITS IN CYCLODEXTRINS
CRAMER, F
MACKENSEN, G
SENSSE, K
[J]. CHEMISCHE BERICHTE-RECUEIL, 1969, 102 (02): : 494 - +
[7] SYNTHESIS OF CHEMICALLY MODIFIED CYCLODEXTRINS
CROFT, AP
BARTSCH, RA
[J]. TETRAHEDRON, 1983, 39 (09) : 1417 - 1474
[8] DEFAYE J, 1990, 5TH INT S CYCL PAR, P90
[9] ELLWOOD P, 1990, 5TH INT S CYCL PAR, P74
[10] SPECIFIC PREPARATION AND STRUCTURE DETERMINATION OF 3A,3C,3E-TRI-O-SULFONYL-BETA-CYCLODEXTRIN
FUJITA, K
TAHARA, T
YAMAMURA, H
IMOTO, T
KOGA, T
FUJIOKA, T
MIHASHI, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (03) : 877 - 880

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