(AROXYMETHYL)TRIPHENYLTIN COMPOUNDS - CRYSTAL AND MOLECULAR-STRUCTURE OF TRIPHENYL(P-TOLOXYMETHYL)TIN

被引：6

作者：

COX, PJ

DOIDGEHARRISON, SMSV

HOWIE, RA

WARDELL, JL

机构：

[1] ROBERT GORDON INST TECHNOL,SCH APPL SCI,ABERDEEN AB1 1HG,SCOTLAND

[2] UNIV ABERDEEN,DEPT CHEM,ABERDEEN AB9 2UE,SCOTLAND

来源：

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1991年 / 21卷 / 06期

关键词：

D O I：

10.1007/BF01179921

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Compounds, Ph3SnCH2OAr, are available from Ph3SnCH2I and NaOAr in EtOH. The crystal and molecular structure of Ph3SnCH2OC6H4Me-p (II) has been determined by X-ray crystallography. The molecule in the crystal contains a slightly distorted tetrahedral tin atom [C-Sn-C valency angles varying from 106.9(5) to 114.1(6)-degrees] with an intramolecular Sn---O distance of 2.900(11) angstrom. NMR spectral data for (II) and for Ph3SnCH2OC6H3Br2-2,4 are reported.

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页码：735 / 739

页数：5

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