PREPARATION AND X-RAY CHARACTERIZATION OF THE 1ST HETEROLEPTIC HYDROCARBON-SOLUBLE TIN(II) PSEUDOHALIDE, SN(NCS) [N(SIME3)2]

被引：20

作者：

CHORLEY, RW

HITCHCOCK, PB

LAPPERT, MF

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 08期

关键词：

D O I：

10.1039/dt9920001451

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of equivalent portions of Sn(NCS)2 and Sn(NR2)2 (R = SiMe3) in Et2O yielded the toluene-soluble, crystalline, colourless Sn(NCS) (NR2), which X-ray crystallography shows to be a V-shaped monomer [N-Sn-N 94.1 (2), Sn-N-CS 171.0(5)-degrees] with weak intermolecular bonding to neighbouring units [Sn...S' 3.047(2) and Sn...S" 3.316(2) angstrom; S'...Sn...S" 178.4(1)-degrees].

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页码：1451 / 1452

页数：2

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