ARENE 1,4-DIRADICAL FORMATION FROM ORTHO-DIALKYNYLARENES

被引：63

作者：

SEMMELHACK, MF

NEU, T

FOUBELO, F

机构：

[1] Department of Chemistry, Princeton University, Princeton

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 23期

基金：

美国国家卫生研究院;

关键词：

DIYNE-ENES; BERGMAN REARRANGEMENT; ARENE-1,4-DIYLS; ORTHO-DIALKYNYLARENES;

D O I：

10.1016/S0040-4039(00)92066-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of five arene and quinone derivatives with dialkynyl substituents in the ortho positions and fixed in a 10-membered ring were prepared and tested with respect to thermal rearrangement to the corresponding arene 1,4 diradicals.

引用

页码：3277 / 3280

页数：4

共 15 条

[11] THE SYNTHESIS OF A 10-MEMBERED BENZO-OXADIYNE RING
SINGH, R
JUST, G
[J]. TETRAHEDRON LETTERS, 1990, 31 (02) : 185 - 188
[12] THE CYCLIZATION OF CALICHEAMICIN-ESPERAMICIN ANALOGS - A PREDICTIVE BIRADICALOID TRANSITION-STATE
SNYDER, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7630 - 7632
[13] MONOCYCLIC ENEDIYNE COLLAPSE TO 1,4-DIYL BIRADICALS - A PATHWAY UNDER STRAIN CONTROL
SNYDER, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (13) : 5367 - 5369
[14] 5,12-DIHYDRO-6,11-DIDEHYDRONAPHTHACENE, A DERIVATIVE OF 1,4-DIDEHYDRONAPHTHALENE
WONG, HNC
SONDHEIMER, F
[J]. TETRAHEDRON LETTERS, 1980, 21 (02) : 217 - 220
[15] ZINCKE T, 1894, CHEM BER, V27, P2753

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