SYNTHESIS OF AN OPTICALLY-ACTIVE HYDROXY DIPHOSPHINE, A NEW LIGAND FOR ASYMMETRIC CATALYSIS

被引：13

作者：

BORNER, A

HOLZ, J

KLESS, A

HELLER, D

BERENS, U

机构：

[1] Max-Planck-Gesellschaft, Arbeitsgruppe für Asymmetrische Katalyse an der Universität Rostock, D-18055 Rostock

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 33期

关键词：

D O I：

10.1016/0040-4039(94)88078-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of (4R,5R)-4,5-bis(diphenylphosphinomethyl) -2-hydroxymethyl-2-phenyl-1,3-dioxolane 1 which is related to DIOP is described. The application of this new ligand in asymmetric catalysis is illustrated in the stereodifferentiating hydrogenation.

引用

页码：6071 / 6074

页数：4

共 17 条

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