COBALT(II) COMPLEX CATALYZED EPOXIDATION OF OLEFINS BY COMBINED USE OF MOLECULAR-OXYGEN AND CYCLIC-KETONES

被引：45

作者：

TAKAI, T

HATA, E

YOROZU, K

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 10期

关键词：

D O I：

10.1246/cl.1992.2077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of cobalt(II)-Schiff base complexes, various olefins are smoothly oxygenated into the corresponding epoxides in good to high yields by combined use of an atmospheric pressure of oxygen (oxidant) and cyclic ketones (reductant), such as 2-methylcyclohexanone, under mild conditions.

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页码：2077 / 2080

页数：4

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