AQUEOUS CATALYTIC DIMERIZATION OF ETHYLENE - CHARACTERIZATION OF THE REACTION INTERMEDIATES [RU(CH2=CH2)(H2O)5](TOS)2 AND [RU(CH2=CH2)2(H2O)4](TOS)2(TOS=TOLUENE-P-SULFONATE)

被引：29

作者：

LAURENCZY, G

MERBACH, AE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000187

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that [Ru(H2O)6]2+ can efficiently catalyse under mild experimental conditions the dimerisation of ethylene in a fully aqueous solution to form butenes ([Z-but-2-ene]: [E-but-2-ene]: [but-1-ene] is 1:2.2:2.2); the reaction intermediates [Ru(CH2=CH2)(H2O)5](tos)2 and [Ru(CH2=CH2)2(H2O)4](tos)2 have been isolated in solid form.

引用

页码：187 / 189

页数：3

共 20 条

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