MULTICAVITANDS .1. SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A BIS P-TERT-BUTYLCALIX[4]ARENE FUSED BY 2 SILICON ATOMS

被引：52

作者：

DELAIGUE, X

HOSSEINI, MW

DECIAN, A

FISCHER, J

LEIZE, E

KIEFFER, S

VANDORSSELAER, A

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,CNRS,CHIM COORDINAT ORGAN LAB,4 RUE BLAISE PASCAL,F-67070 STRASBOURG,FRANCE

[2] UNIV STRASBOURG 1,INST LE BEL,CNRS,CRISTALLOCHIM & CHIM STRUCT,F-67070 STRASBOURG,FRANCE

[3] UNIV STRASBOURG 1,INST CHIM,CNRS,SPECTROMETRIE MASSE BIOORGAN LAB,F-67070 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)73683-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a receptor possessing two divergent hydrophobic cavities was achieved by fusing two p-tert-butylcalix[4]arene units in cone conformation using silicon atoms. Crystal structure analysis and NMR studies proved the centrosymetric nature of the compound with a 3.75 angstrom distance between the two tetra-coordinated silicon atoms.

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页码：3285 / 3288

页数：4

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