ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC ALKYLATION WITH PHOSPHORUS-CONTAINING C-2-SYMMETRICAL CHIRAL AMINE LIGANDS

被引：94

作者：

KUBOTA, H

KOGA, K

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

[2] DAIICHI PHARMACEUT CO LTD,TOKYO R&D CTR,EDOGAWA KU,TOKYO 134,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)73469-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of the palladium complex with the phosphorus-containing C-2-symmetric chiral amine ligand 2. 3, the asymmetric allylic substitution of racemic 1,3-diphenyl-2-propenyl acetate 8 with dimethyl malonate proceeded in high yield with remarkable enantiomeric excess.

引用

页码：6689 / 6692

页数：4

共 17 条

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