PALLADIUM-CATALYZED ASYMMETRIC HYDROPHENYLATION OF 1,4-DIHYDRO-1,4-EPOXYNAPHTHALENE

被引:70
作者
MOINET, C [1 ]
FIAUD, JC [1 ]
机构
[1] UNIV PARIS 11,CNRS,INST CHIM MOLEC ORSAY,F-91405 ORSAY,FRANCE
关键词
D O I
10.1016/0040-4039(95)00178-F
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium-catalyzed hydrophenylation of 7-oxybenzonorbornene with phenyl iodide or triflate in the presence of formate afforded 1,4-epoxy-2-phenyl-1,2,3,4-tetrahydronaphthalene and (1R*,2S*)-1,2-dihydro-2-phenylnaphthalen-1-ol. Both product distribution and enantioselectivity for these compounds were dependent of the leaving group of the substrate and the ligand of the catalyst.
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页码:2051 / 2052
页数:2
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