BIOSYNTHETIC-STUDIES ON POLYPROPIONATES - A STEREOCHEMICAL MODEL FOR SIPHONARIN-A AND SIPHONARIN-B FROM THE PULMONATE LIMPET SIPHONARIA ZELANDICA

被引：33

作者：

GARSON, MJ

JONES, DD

SMALL, CJ

LIANG, J

CLARDY, J

机构：

[1] UNIV WOLLONGONG,DEPT CHEM,WOLLONGONG,NSW 2500,AUSTRALIA

[2] CORNELL UNIV,BAKER LAB,DEPT CHEM,NEW YORK,NY 14853

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 37期

关键词：

D O I：

10.1016/0040-4039(94)85042-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The pattern of incorporation of sodium [1-C-14]propionate and sodium [2,3-C-14(2)]succinate into siphonarins A (1) and B (2), metabolites of the pulmonate limpet S. zelandica, is determined by chemical degradation. The absolute configuration of (1) is revised by an x-ray study on the p-bromophenylboronate derivative, and together with the chain building pattern, defines a biosynthetic model for these siphonariid polypropionates.

引用

页码：6921 / 6924

页数：4

共 27 条

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