INFLUENCES OF ELECTROLYTIC CONDITIONS ON EMULSION ELECTROLYSIS - N-OCTANOL OXIDATION

被引：6

作者：

CHEN, PC ^{[1
]}

NONAKA, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT ELECTR CHEM,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

DENKI KAGAKU | 1995年 / 63卷 / 05期

关键词：

EMULSION ELECTROLYSIS; N-OCTANOL OXIDATION; ELECTROLYTIC CONDITION;

D O I：

10.5796/kogyobutsurikagaku.63.395

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Influences of electrolytic conditions on emulsion electrolysis were investigated using the electrooxidation of n-octanol on nickel anodes in strongly alkaline solutions as a model reaction. It was found that n-octanol molecules dissolved in the solution are oxidized on an ordinary hydrophilic anode covered with nickel oxide films while its droplets are not. This was also supported from manner of the influences of amount of n-octanol, surfactant, quaternary ammonium salt and agitation on current efficiency for the oxidation. As result, some general guidelines for efficiently conducting emulsion electrolysis were obtained.

引用

页码：395 / 399

页数：5

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