ELECTROLYSIS OF EMULSIONS OF ORGANIC-COMPOUNDS ON HYDROPHOBIC ELECTRODES

被引:20
作者
KUNUGI, Y [1 ]
CHEN, PC [1 ]
NONAKA, T [1 ]
CHONG, YB [1 ]
WATANABE, N [1 ]
机构
[1] APPL SCI RES INST,SAKYO KU,KYOTO 606,JAPAN
关键词
D O I
10.1149/1.2220918
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Suspensions of some water-insoluble organic compounds, such as alcohols, amines, activated olefines, and dibromobenzene, were electrolyzed efficiently on a hydrophobic electrode prepared by composite-plating nickel with tetrafluoroethylene oligomer (TFEO) particles. This result suggests a useful method for suspension electrolysis from a practical aspect and a hypothesis (organic droplet-collecting effect) that the hydrophobic electrode surface is covered by thin films of the organic compounds and consequently the electrolysis of water (oxygen and hydrogen evolution) is suppressed.
引用
收藏
页码:2833 / 2836
页数:4
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